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Abstract:
In this work, single-phase spherical Nd-Fe-B regenerated single crystals powder (SRP) was recycled via calcium reduction method from sintered Nd-Fe-B (S-NdFeB) sludge, followed by blending with high remanence alloy (HRA) and Pr-rich alloy at varying weight ratios from 45 % to 85 % for fabricating regenerated magnets (RM). We conducted a series of analyses of phases, microstructures, magnetic performance, and magnetization reversal behaviors on the RM samples, expounding the SRP proportion impacts and the magnetic recovery mechanism. With the increasing SRP proportion, the comprehensive magnetic performance exhibits a trend of initially raising and then decreasing, reaching a summit for magnet RM-65 %. Br, (BH)max and the squareness (Hk/Hcj) are well recovered to 103.8 %, 104.5 %, and 102.2 % of the original magnet, respectively due to the high orientation induced by SRP, the high Br from HRA alloy, and uniform grain size. Hcj is recovered to 73.1 % with a satisfying value exceeding 15 kOe. The introduction of Pr-rich alloy facilitates the formation of thin, continuous grain boundaries, enhancing the magnetic isolation effect between the main phase grains; on the other hand, the Pr-rich-shell structure with high anisotropic field, and the chemical heterogeneity of the multiple main phase grains, improve the nucleation field of the reversed domain, contributing to the high Hcj together. © 2024
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Sustainable Materials and Technologies
ISSN: 2214-9929
Year: 2025
Volume: 43
9 . 6 0 0
JCR@2022
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 11
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