Considering　the　prevalence　of　cyberbullying,　the　current　study　explores　the　factors　associated　with　its　perpetration.　Using　self-determination　theory,　the　association　of　parental　psychological　control　(PPC)　with　cyberbullying　perpetration　was　examined.　To　explore　this　influencing　mechanism　further,　psychological　reactance　(PRt)　and　materialism　were　examined　as　two　mediators　in　this　relationship.　Moreover,　according　to　the　diathesis-stress　model　and　cognitive　model　of　resilience,　psychological　resilience　(PRl)　was　examined　as　a　moderator　in　the　direct　and　indirect　link　between　PPC　and　cyberbullying　perpetration.　To　test　our　expectations,　804　adolescents　(M　=　13.12,　SD　=　1.16)　participated　in　the　current　study　using　a　cross-sectional　design　and　multiple　questionnaires,　namely,　the　Chinese　version　of　the　Parental　Control　Questionnaire,　Revised　Cyber　Bullying　Inventory,　Hong　Psychological　Reactance　Scale,　Material　Values　Scale　for　Children,　and　Resilience　Scale　for　Chinese　Adolescents.　Correlation　analysis　indicated　that　PPC,　PRt,　materialism,　and　cyberbullying　perpetration　were　significantly　and　positively　correlated,　and　were　significantly　and　negatively　related　to　PRl.　Moderated　mediation　analysis　revealed　that　PRt　and　materialism　played　multiple　mediating　roles　in　the　relationship　between　PPC　and　cyberbullying　perpetration.　Multiple　mediation　analysis　indicated　that　PRl　weakened　the　direct　associations　of　PPC,　PRt,　and　materialism　with　cyberbullying　perpetration,　further　alleviating　the　indirect　and　direct　associations　of　PPC　with　cyberbullying　perpetration,　supporting　the　moderated　mediation　model.　Specifically,　adolescents　high　in　PPC　were　more　likely　to　have　stronger　PRt　and　materialistic　values,　which　further　triggered　cyberbullying　perpetration.　PRl　can　protect　adolescents　high　in　PPC　from　cyberbullying　perpetration　via　weakening　the　direct　and　indirect　associations　of　PPC　with　cyberbullying.