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Author:

Liao Yi-min (Liao Yi-min.) | Yan Yin-zhou (Yan Yin-zhou.) | Wang Qiang (Wang Qiang.) | Yang Li-xue (Yang Li-xue.) | Pan Yong-man (Pan Yong-man.) | Xing Cheng (Xing Cheng.) | Jiang Yi-jian (Jiang Yi-jian.)

Indexed by:

EI Scopus SCIE

Abstract:

ZnO is third-generation semiconductors which can be used as the carrier of ultraviolet photoluminescence and multiresonance mode laser. In recent years, ZnO microcrystals prepared by optical vapor supersaturation precipitation (OVSP) have shown important advantages in photocatalysis, efficient multi-color light source and efficient electroluminescence. However, the high preparation cost and low production efficiency hinder the development of the large-scale device. In this work, we designed and built a set of growth devices with a working wavelength of 1 080 nm and a power of 18% (@2 500 W) laser heating. The height of the raw material rod was 6. 5 mm, and the diameter was 8 mm. The results show that the morphology, structure, and luminescence properties of the products prepared by this device are very close to those prepared by the OVSP method, and the production efficiency is greatly improved (similar to 500 %). The growth device successfully prepared acceptor-rich ZnO single crystal micro rods with complete hexagonal cross-section morphology. The diameter and length of ZnO micro rods are about 3. 8 and 10 similar to 20 mu m, respectively. Raman spectra show that the Raman peaks of ZnO micro rods are sharp, and the Raman mode at 437 cm(-1) indicates that the ZnO micro rods are hexagonal wurtzite structures with good crystallinity. By analysing the PL spectra of ZnO micro rods, it was found that the ZnO microtubes prepared by the OVSP method had a similar ultraviolet bimodal structure, indicating that there exists an abundant zinc-vacancies acceptor. In the 80 similar to 280 K range, with the increase of temperature, the fluorescence intensity of ZnO microrods appears "thermal quenching-negative thermal quenching-thermal quenching" behavior. The negative thermal quenching behavior in the range of 166 similar to 200 K is related to the intermediate state energy level (trap center) at 477 meV below the conduction band bottom, and the thermal quenching phenomenon in the range of 200 similar to 280 K is related to the non-radiative recombination center at 600 meV below the conduction band bottom. The appearance of both is related to the prepared ZnO microrod oxygen vacancy (V-o) defect. The laser growth device developed in this paper has high feasibility and practicability. This preparation method lays a technical foundation for the rapid batch growth of ZnO single crystal micro rods with rich acceptors and is also of great significance for its application in optoelectronic devices.

Keyword:

PL spectrum Raman spectrum Laser material processing ZnO microcrystal

Author Community:

  • [ 1 ] [Liao Yi-min]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Yan Yin-zhou]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Pan Yong-man]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Xing Cheng]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Jiang Yi-jian]Beijing Univ Technol, Fac Mat & Mfg, Inst Laser Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang Qiang]Beijing Inst Petrochem Technol, Coll New Mat & Chem Engn, Beijing 102617, Peoples R China
  • [ 7 ] [Jiang Yi-jian]Beijing Inst Petrochem Technol, Coll New Mat & Chem Engn, Beijing 102617, Peoples R China
  • [ 8 ] [Yang Li-xue]Beijing Inst Graph Commun, Sch Printing & Packing Engineer, Beijing 102627, Peoples R China

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Source :

SPECTROSCOPY AND SPECTRAL ANALYSIS

ISSN: 1000-0593

Year: 2022

Issue: 10

Volume: 42

Page: 3000-3005

0 . 7

JCR@2022

0 . 7 0 0

JCR@2022

ESI Discipline: CHEMISTRY;

ESI HC Threshold:53

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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