The　painting　and　electronics　industries　simultaneously　release　aromatic　compounds　and　chlorinated　organics.　The　development　of　catalysts　with　synergistic　control　of　these　pollutants　is　of　great　significance　to　achieve　air　purification.　However,　developing　active　catalysts　while　maintaining　good　chlorine　resistance　remain　a　huge　challenge　due　to　the　difficulty　of　the　trade-off　between　the　redox　properties　and　acidity　and　the　production　of　polychlorinated　byproducts.　Herein,　we　introduce　a　novel　tandem　PtSn/CeO2　&　Mn/ZSM-5　catalyst　and　investigate　its　catalytic　performance　for　multicomponent　volatile　organic　compounds　(VOCs)　oxidation.　The　two　individual　catalysts,　PtSn/CeO2　and　Mn/ZSM-5,　were　used　to　catalyze　two　distinct　sequential　reactions.　PtSn/CeO2　catalyzed　toluene　oxidation　to　produce　CO2　and　H2O.　Meanwhile,　the　introduction　of　SnOx　favored　the　adsorption　of　trichloroethylene　(TCE)　molecules　that　prevented　Pt　sites　from　chlorine　poisoning　and　possibly　converted　adsorbed　TCE　into　intermediates,　which　were　subsequently　oxidized　deeply　by　the　nearby　Mn/ZSM-5.　This　approach　resulted　in　a　remarkable　oxidation　efficiency　for　toluene　(T90　=　296　degrees　C)　and　TCE　(T90　=　384　degrees　C),　with　fewer　unexpected　toxic　byproducts　(chlorobenzene　and　4-chlorotoluene).　Furthermore,　the　tandem　catalyst　possessed　excellent　chlorine　and　water　resistances.　In　conclusion,　the　above　findings　provide　new　insights　into　the　design　and/or　syntheses　of　advanced　catalysts　for　widespread　VOCs　pollution　control.