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Author:

Wu, Xin (Wu, Xin.) | Tong, Zhuang (Tong, Zhuang.) | Liu, Yunliang (Liu, Yunliang.) | Li, Yaxi (Li, Yaxi.) | Cheng, Yuanyuan (Cheng, Yuanyuan.) | Yu, Jingwen (Yu, Jingwen.) | Cao, Peng (Cao, Peng.) | Zhuang, Chunqiang (Zhuang, Chunqiang.) | Shi, Qiuzhong (Shi, Qiuzhong.) | Liu, Naiyun (Liu, Naiyun.) | Liu, Xiang (Liu, Xiang.) | Liang, Hongyu (Liang, Hongyu.) | Li, Haitao (Li, Haitao.)

Indexed by:

EI Scopus SCIE

Abstract:

Electrochemical carbon dioxide reduction reaction (CO2RR) can produce value-added hydrocarbons from renewable electricity, providing a sustainable and promising approach to meet dual-carbon targets and alleviate the energy crisis. However, it is still challenging to improve the selectivity and stability of the products, especially the C2+ products. Here we propose to modulate the electronic structure of copper oxide (CuO) through lattice strain construction by zinc (Zn) doping to improve the selectivity of the catalyst to ethylene. Combined performance and in situ characterization analyses show that the compressive strain generated within the CuO lattice and the electronic structure modulation by Zn doping enhances the adsorption of the key intermediate (CO)-C-star, thereby increasing the intrinsic activity of CO2RR and inhibiting the hydrogen precipitation reaction. Among the best catalysts had significantly improved ethylene selectivity of 60.5% and partial current density of 500 mAcm(-2), and the highest C2+ Faraday efficiency of 71.47%. This paper provides a simple idea to study the modulation of CO2RR properties by heteroatom doped and lattice strain.

Keyword:

ethylene selectivity lattice strain heteroatom-doped CO2 reduction

Author Community:

  • [ 1 ] [Wu, Xin]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 2 ] [Tong, Zhuang]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 3 ] [Liu, Yunliang]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 4 ] [Li, Yaxi]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 5 ] [Cheng, Yuanyuan]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 6 ] [Yu, Jingwen]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 7 ] [Cao, Peng]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 8 ] [Liu, Naiyun]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 9 ] [Li, Haitao]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China
  • [ 10 ] [Zhuang, Chunqiang]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 11 ] [Shi, Qiuzhong]Zhenjiang Coll, Inst Med & Chem Engn, Zhenjiang 212028, Peoples R China
  • [ 12 ] [Liu, Xiang]Zhenjiang Coll, Inst Med & Chem Engn, Zhenjiang 212028, Peoples R China
  • [ 13 ] [Liang, Hongyu]Jiangsu Univ, Inst Adv Mfg & Modern Equipment Technol, Sch Mech Engn, Zhenjiang 212013, Peoples R China

Reprint Author's Address:

  • [Liu, Naiyun]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China;;[Li, Haitao]Jiangsu Univ, Inst Energy Res, Sch Energy & Power Engn, Zhenjiang 212013, Peoples R China;;[Liu, Xiang]Zhenjiang Coll, Inst Med & Chem Engn, Zhenjiang 212028, Peoples R China;;

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Source :

NANO RESEARCH

ISSN: 1998-0124

Year: 2024

Issue: 8

Volume: 17

Page: 7194-7202

9 . 9 0 0

JCR@2022

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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