A　MOF-derived　carbon　material　containing　CoFe　alloy　(Co/Fe@NPC-500)　by　calcining　N-doped　Co/Fe　bimetallic　MOF　at　a　lower　temperature　was　successfully　synthesized　as　a　cathode　in　electro-Fenton　process　for　ceftazidime　(CAZ)　degradation.　The　presence　of　Co　could　accelerate　the　transfer　of　electrons　from　C　atoms　of　carbon　material　to　Fe,　thus　increasing　the　content　of　low-valent　metals　in　the　material,　which　had　been　demonstrated　by　char-acterizations　and　density　functional　theory　(DFT)　calculations.　Thanks　to　the　integrity　of　the　MOF　structure,　the　synergistic　effect　between　Fe　and　Co,　Co/Fe@NPC-500　cathode　showed　efficient　removal　efficiency　for　CAZ　completely　removed　within　60　min　and　obtained　a　total　organic　carbon　(TOC)　removal　rate　of　52.1%　at　90　min.　Besides,　based　on　the　results　of　HPLC-MS　and　DFT　calculations,　the　degradation　pathway　of　CAZ　was　proposed.　This　study　provides　some　useful　information　for　the　preparation　of　MOF-derived　carbon　materials　containing　low-valent　metals　for　electro-Fenton　process.